{{page>wiki:headers:hheader}} =====Using the Equipartition Theorem to Estimate Heat Capacity (10 minutes)===== * Recall that the equipartition theorem is the formula relating the temperature of a sample to it's average total energy. * //**Example: solids at room temperature and above.**// - $k_{B}T$ is the energy stored in each normal mode of a crystal. - For each normal mode, $\frac{k_{B}T}{2}$ stored as kinetic energy, $\frac{k_{B}T}{2}$ stored as potential energy. - $\text{# of normal modes}= \left(\text{# atoms in crystal}\right) * \left(\text{# dimensions}\right)$ - From the above information, $$U_{Tot}=\left(\text{# modes}\right) * k_{B}T \; \; . $$ * Now, using the equation for the total energy of any system, we can approximate the heat capacity of the system using $$C_{\alpha} \, = \, \left(\frac{dU_{tot}}{dT}\right)_{\alpha} \; \; , $$ Where $\alpha$ is the variable of the system being held constant (volume, pressure, etc.). * As a wrap-up for this lecture, [[..:..:..:courses:activities:ppact:ppspecheatwater|Finding the Specific Heat of Water]] is a helpful example to clarify any confusion. {{page>wiki:footers:courses:ppfooter}}